Theoretical Considerations
The expandable mold is
formed of refractory materials. The thermal conductivity of the
mold is a property of the material selected. It is also a function
of particle size and distribution. The thermal conductivity influences
the rate of transfer through the mold and therefore the rate of
solidification which, in turn, influence the metallurgical integrity
of the casting.
When choosing the mold
material, it must be sufficiently refractory to withstand the pouring
temperature of the particular metal being cast without melting or
softening. Providing the material is pure, the melting point value
is a good guide to refractoriness. However, the melting points can
be reduced severely by adding very small amounts of alkali metal
salts or iron oxide.
The refractory selected
should exhibit stability. It should not be susceptible to hydration,
or reaction with other materials in the mold or the metal.
It should also be thermally
stable, i.e., expansion should be predictable, constant and reproducible.
It can be taken into account when estimating the contraction allowance
for the casting.
Following is a table
of some refractory material characteristics:
| Refractory
Material |
Chemical
Notation |
Melting
Point
(deg C)
|
Coefficient
of Thermal Expansion/ ( deg C) |
| Alumina |
Al2O3 |
2050 |
9.5 x10
-6 |
| Fused
Silica |
SiO2 |
1710 |
0.5 x10
-6 |
| Mullite |
3Al2O3.2SiO2 |
1810 |
6.0 x10
-6 |
Information
source: Clegg, Precision Casting Processes.
|